Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3 P,P′,P′′)cobaltate(III)-κ3 O,O′,O′′]oxovanadium(IV)}-μ-oxalate
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چکیده
منابع مشابه
Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3 P,P′,P′′)cobaltate(III)-κ3 O,O′,O′′]oxovanadium(IV)}-μ-oxalate
The title compound {systematic name: bis[1,4(η(5))-cyclo-penta-dien-yl]hexa-kis(μ-diethyl phosphito)-1:2κ(6)P:O;3:4κ(6)O:P-μ-ox-alato-2:3κ(4)O(1),O(2):O(1'),O(2')-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion cente...
متن کاملcatena-Poly[cobalt(II)-bis(μ-2-aminoethanesulfonato)-κ3 N,O:O′;κ3 O:N,O′]
The hydro-thermally prepared title compound, [Co(C(2)H(6)NO(3)S)(2)](n), is isotypic with its Ni(II) analogue. The Co(II) cation is in a distorted octa-hedral environment, coordinated by four sulfonate O atoms and two N atoms from the taurine ligands. In comparison with the Ni(II) analogue, the Co-N and Co-O bonds are longer than the Ni-N and Ni-O bonds, whereas all other bond lengths and angle...
متن کاملPoly[aqua(μ-pyrazine-2-carboxylato-κ3 N,O:O)(μ-pyrazine-2-carboxylato-κ3 N,O:O′)lead(II)]
The polymeric structure of the title compound, [Pb(C(5)H(3)N(2)O(2))(2)(H(2)O)](n), is built up from centrosymmetric [Pb(C(5)H(3)N(2)O(2))(2)(H(2)O)](2) dimers, which are bridged by ligand carboxyl-ate O atoms. The Pb(II) ion adopts an irregular PbN(2)O(5) coordination polyhedron; it is chelated by one N,O-bidentate ligand and also bonds to a water O atom. A second N,O-bidentate ligand forms th...
متن کاملcatena-Poly[nickel(II)-bis(μ-2-aminoethanesulfonato-κ3 N,O:O′;κ3 O:N,O′)]
In the title polymeric complex, [Ni(C(2)H(6)NO(3)S)(2)](n), the Ni(II) ion occupies a special position on an inversion centre and displays a slightly distorted octa-hedral coordination geometry, being linked to four sulfonate O atoms and to two N atoms of the taurine ligands. The sulfonate groups doubly bridge symmetry-related Ni(II) centers, forming polymeric chains along the a axis.
متن کاملBis(μ-quinolin-8-olato)-κ3 N,O:O;κ3 O:N,O-bis[chloridomethylphenyltin(IV)]
The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa-hedral coordination [C-Sn-C = 157.83 (8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter-molecular C-H⋯Cl...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808024458